Advances in Supramolecular Chemistry. Volume 7 - download pdf or read online

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By G.W. Gokel

ISBN-10: 0762306785

ISBN-13: 9780762306787

This quantity provides various articles that surround the extensive scope of supramolecular chemistry. Reusch's bankruptcy covers organic channel compounds, whereas the paintings of corridor and Kirkovits appears to be like into their artificial opposite numbers. steel ion sensors, calixarenes and ''crystal engineering'' are defined by way of pioneers in those fields. This paintings, when present and authoritative, exhibits us that a lot is still undertaken and understood. it really is was hoping that this quantity should be of curiosity to people who desire to fill those gaps; scientists already within the box and those that might even see extensions in their personal paintings that might carry them into it.

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J. Org. Chem- 1996, 61, 8866-8874 and references cited therein. 26. Gokel, G. ; Murillo, O. Acc. Chem- Res. 1996, 29, 425-432. 27. Fyles, T. M. Current Opin. Chem. Biol. 1997, I, 497-505. 28. ; Yokota, K. Tetrahedron Lett. 1982, 23, 4601-4604. 29. ; Moras, D. Nature 1982, 295, 526-527. 30. (a) Neeval, J. ; Nolte, R. J. M. Tetrahedron Lett. 1984, 25, 2263-2266. (b) Kragten, U. E; Roks, M. ; Nolte, R. J. M. J. , Chem. Commun. 1985, 1275-1276. 31. ; Davis, D. ; Persichetti, R. -J. J. Am. Chem- Soc.

C. ; Woolley, G. A. J. Am. Chem- Soc. 1996,118, 12222-12223. 23. (a) Stankovic, C. ; Heinemann, S. ; Delfino, J. ; Schreiber, S. L. Science 1989, 244, 813-817. (b) Stankovic, C. ; Heinemann, S. ; Schreiber, S. L. J. Ant Chem- Soc. 1990, 112, 3702-3704. 24. Schmitt, J. ; Sansom, M. S. E; Kerr, I. ; Lunt, G. ; Eisenthal, R. Biochemistry 1997, 36, 1115-1122. 25. Fyles, T. ; van Straaten-Nijenhuis, W. E; Zhou, X. J. Org. Chem- 1996, 61, 8866-8874 and references cited therein. 26. Gokel, G. ; Murillo, O.

Permeability ratio between K § and CI- was found to be ca. 5 which is consistent with the oligoether chains acting as the cation-conducting pore. 5 M KCI were almost identical. Interestingly, the single-alkyl chain analogues of 39 were unable to form stable ionic channels. By replacing the carboxylate group of 39 (electrically neutral) with phosphate (40), an overall negative charge was introduced to the head group. 55 Consequently, it was proposed that the resultant dipole of 40 would give rise to voltage-gated activity.

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Advances in Supramolecular Chemistry. Volume 7 by G.W. Gokel

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