Inorganic

Activation and Catalytic Reactions of Saturated Hydrocarbons by A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov PDF

Posted On April 18, 2018 at 8:40 pm by / Comments Off on Activation and Catalytic Reactions of Saturated Hydrocarbons by A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov PDF

By A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov

ISBN-10: 0306469456

ISBN-13: 9780306469459

ISBN-10: 0792361016

ISBN-13: 9780792361015

This monograph is dedicated to the activation and diverse variations of saturated hydrocarbons (alkanes), i.e. reactions followed through the C--H and C--C bond cleavage. Alkanes are the most elements of oil and usual fuel, and as a result are the vital feedstocks for the chemical undefined. however, those elements are identified to be the least reactive natural compounds. detailed cognizance is paid to the lately stumbled on alkane activations in the presence of steel complexes, that are defined in additional element. as well as the reactions of saturated hydrocarbons that are the major subject of this ebook, the activation of C--H bonds in arenes or even olefins and acetylenes are thought of. The monograph may be beneficial not just if you have an interest in the activation of alkanes and different hydrocarbons by way of steel complexes, but additionally for experts in homogeneous and heterogeneous catalysis, petrochemistry, and organometallic chemistry. a few components of the monograph might be of curiosity for experts in inorganic and natural chemistry, theoretical chemistry, biochemistry or even biology, and additionally when you paintings within the petrochemical undefined, business natural synthesis and biotechnology.

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Read or Download Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes Category should be: CHEMISTRY PDF

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Additional info for Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes Category should be: CHEMISTRY

Example text

It was demonstrated that palladium(II) derivatives induce the oxidative coupling of arenes [9a] and also the arylation of alkenes [9b], while platinum(II) salts catalyze the H–D exchange between benzene and [9c]. In 1969 the first 18 CHAPTER I (Rets. p. 19) reactions involving activation of C–H bond in alkanes were discovered [10]: it was found that platinum(II) salts catalyze the H–D exchange between methane or its analogs and at 100 °C and the complex induces the deuteration of methane by at room temperature.

69) carbons with anion in the presence of cerium ammonium nitrate proceeds as a radical reaction [18a]: Bromination of toluene by the system products: gives three main The free-radical bromination by occurs in ethyl acetate yielding and while the ring-bromination by occurs in aqueous acetonitrile [18b]. Photochemical reaction of 4-tert-butyltoluene with gives benzyl bromide easily hydrolyzed to 4-tert-butylbenzaldehyde [18c]. Thermal and photochemical bromination of decalin gives mainly tetrabromooctalin [18d]: Adamantane has been brominated with the system transfer catalysis conditions [18e]: under phase Transformations in the Absence of Metals The reaction is believed to be initiated by single-electron oxidation of 33 by The behavior of 1 -adamantyl radical in chlorine atom abstraction has been investigated recently [18f].

Of the aromatic nucleus [8a] and of a -hybridized carbon atom [8b] were found. It was demonstrated that palladium(II) derivatives induce the oxidative coupling of arenes [9a] and also the arylation of alkenes [9b], while platinum(II) salts catalyze the H–D exchange between benzene and [9c]. In 1969 the first 18 CHAPTER I (Rets. p. 19) reactions involving activation of C–H bond in alkanes were discovered [10]: it was found that platinum(II) salts catalyze the H–D exchange between methane or its analogs and at 100 °C and the complex induces the deuteration of methane by at room temperature.

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Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes Category should be: CHEMISTRY by A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov


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